JEE Chemistry Practice Question
A trinitro compound, 1,3,5-tris-(4-nitrophenyl)benzene, on complete reaction with an excess of $\mathrm{Sn} / \mathrm{HCl}$ gives a major product, which on treatment with an excess of $\mathrm{NaNO}_{2} / \mathrm{HCl}$ at $0{ }^{\circ} \mathrm{C}$ provides $\mathbf{P}$ as the product. $\mathbf{P}$, upon treatment with excess of $\mathrm{H}_{2} \mathrm{O}$ at room temperature, gives the product $\mathbf{Q}$. Bromination of $\mathbf{Q}$ in aqueous medium furnishes the product $\mathbf{R}$. The compound $\mathbf{P}$ upon treatment with an excess of phenol under basic conditions gives the product $\mathbf{S}$. The molar mass difference between compounds $\mathbf{Q}$ and $\mathbf{R}$ is $474 \mathrm{~g} \mathrm{~mol}^{-1}$ and between compounds $\mathbf{P}$ and $\mathbf{S}$ is $172.5 \mathrm{~g} \mathrm{~mol}^{-1}$. What is the number of heteroatoms present in one molecule of $\mathbf{R}$? [Use: Molar mass (in g mol${ }^{-1}$ ): $\mathrm{H}=1, \mathrm{C}=12, \mathrm{~N}=14, \mathrm{O}=16, \mathrm{Br}=80, \mathrm{Cl}=35.5$ Atoms other than $\mathrm{C}$ and $\mathrm{H}$ are considered as heteroatoms]
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