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JEE Chemistry Practice Question

An acidified solution of $0.05 \mathrm{M} \mathrm{Zn}^{2+}$ is saturated with $0.1 \mathrm{M} \mathrm{H}_{2} \mathrm{~S}$. What is the minimum molar concentration (M) of $\mathrm{H}^{+}$required to prevent the precipitation of $\mathrm{ZnS}$ ? Use $K_{\mathrm{sp}}(\mathrm{ZnS})=1.25 \times 10^{-22}$ and overall dissociation constant of $\mathrm{H}_{2} \mathrm{~S}, K_{\mathrm{NET}}=K_{1} K_{2}=1 \times 10^{-21}$.

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