JEE Chemistry Practice Question
Consider an electrochemical cell: $\mathrm{A}(\mathrm{s})\left|\mathrm{A}^{\mathrm{n}+}(\mathrm{aq}, 2 \mathrm{M}) \| \mathrm{B}^{2 \mathrm{n}+}(\mathrm{aq}, 1 \mathrm{M})\right| \mathrm{B}(\mathrm{s})$. The value of $\Delta H^{\theta}$ for the cell reaction is twice that of $\Delta G^{\theta}$ at $300 \mathrm{~K}$. If the emf of the cell is zero, what is the $\Delta S^{\ominus}$ (in $\mathrm{J} \mathrm{K}^{-1} \mathrm{~mol}^{-1}$ ) of the cell reaction per mole of $\mathrm{B}$ formed at $300 \mathrm{~K}$? (Given: $\ln (2)=0.7, R$ (universal gas constant) $=8.3 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1} . H, S$ and $G$ are enthalpy, entropy and Gibbs energy, respectively.)
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